Sec 1.16 Introduction to Acids and Bases
Prob. 24 (a, 1-2) 25 (b, 1-2), 25
Sec 1.21 Lewis Acids and Bases
Prob. 45 (a,c - show all formal charges!), 46 (a,c,d,e,h)
Sec 1.17 pKa's
Prob 26,29, 30 (a), 31 32 (a,b)
Sec 1.18 Structural effects - VERY IMPORTANT SECTION!!!!!
Prob 33, 34, 37, 38*
Sec 1.19 Resonance Effects on pKa
Prob. 39*
Some excellent problems to tie things together:
Prob 63, 64 (do without looking up pKa's!*)
* indicates a somewhat more challenging problem
Resonance
Sec 6.1, 6.2 Bonding in Benzene
Prob 2
Sec 6.6 Resonance Energy
Sec 6.3-6.5 Resonance
Prob. 3, 4, 14, 16, 17 (2,3,5,8,9,12,17), 18, 19
Sec 6.10 Resonance effects on pKa
Prob 9,10 (a,c), 24 (a-c), 28
More good resonance…..
13 (a-d,k-m), 15(a,d), 17(1-3,10,16), 20, 21